Repeat_unit

An essential concept which defines polymer structure, the repeat unit is the simplest structural unit of a polymer chain. So a polymer consists of repeat units linked together, like the beads of a necklace. One of the simplest repeat units is that of polyethylene:

-[CH₂-CH₂-]_n-

while polypropylene has the repeat unit

-[CH₂-CH(CH₃)]_n-

The subscript "n" denotes the degree of polymerisation, that is, the number of units linked together. The molecular mass of the repeat unit, M_R, is simply the sum of the atomic masses of the atoms within the repeat unit. The molecular mass of the chain is just the product nM_R. Other than monodisperse polymers, there is normally a molar mass distribution caused by chains of different length.

Vinyl Polymers

More complex repeat units occur in vinyl polymers, where one of the hydrogen atoms is substituted by another different atom, or by a larger fragment. So PVC for example possesses a chain in which the hydrogen atom is substituted by a chlorine atom:

-[CH₂-CHCl]_n-

Polystyrene has a backbone chain where the subsituent is now a benzene ring (C₆H₆):

-[CH₂-CH(C₆H₆)]_n-

Also See

• Copolymers
• Polymers

References

• Structure of polymer chains

This article is licensed under the GNU Free Documentation License. It uses material from Wikipedia